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Aluminum Doping of Epitaxial Silicon Carbide
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Authors
U. Forsberg, O. Danielsson, A. Henry, E. Janzen Linkoping University M.K. Linnarsson Royal Institute of Technology
Abstract
Intentional doping of aluminum in 4H and 6H SiC has been performed using a hot-wall CVD reactor. The dependence of aluminum incorporation on temperature, pressure, C/Si ratio, growth rate, and TMA flow has been investigated. The aluminum incorporation showed to be polarity dependent. The high aluminum incorporation on the Si-face is closely related to the carbon coverage on the SiC surface. Changes in process parameters changes the effective C/Si ratio close to the SiC surface. Increased growth rate and C/Si ratio increases the aluminum incorporation on the Si-face. Diffusion limited incorporation occurs at high growth rate. Reduced pressure increases the effective C/Si ratio, and at low growth rate, the aluminum incorporation increases initially, levels off at a critical pressure, and continues to decrease below the critical pressure. The aluminum incorporation showed to be constant in a temperature range of 50C. The highest atomic concentration of aluminum observed in this study was 31017 and 81018 cm3 in Si and C-face, respectively.
Keywords
A1. Doping; A1. Growth models; A3. Chemical vapor deposition processes; A3. Hot wall epitaxy; B2. Semiconducting silicon carbide
Source
Journal of Crystal Growth 253 (2003) 340–350
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