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Development of Intermediate-Temperature Solid Oxide Fuel Cells for Hydrocarbon Fuels
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Authors
Norihisa Chitose, Takashi Miyazawa, Katsuya Hirata, Shigeru Sato, Makoto Shibata, Kei Hosoi, Taner Akbay, Jun Akikusa, Shin Nakamura, Takafumi Kotani, Naoya Murakami, Takashi Yamada, Masaharu Yamada, Akihiro Hasegawa, Norikazu Komada Mitsubishi Materials Corporation Futoshi Nishiwaki, Toru Inagaki, Jiro Kano, Satoshi Ujiie, Hiroaki Nakajima, Junya Nishi, Tsunehisa Sasaki, Hiroyuki Yoshida, Koji Hashino, Mitsunobu Kawano, Satoru Yamasaki Kansai Electric Power Co. Tatsumi Ishihara Kyushu University Yusaku Takita Oita University
Abstract

Mitsubishi Materials Corporation (MMC) and The Kansai Electric Power Co., Inc. (KEPCO) have been jointly developing intermediate-temperature (IT) solid oxide fuel cells (SOFCs). The primary target of collaboration is the development of modular and scalable SOFC systems for on-site power generation. Planar disk-type cells with the diameter of 120 mm have shown excellent performance between 700 and 800 °C due to highly efficient oxide-ion conducting electrolyte made of doped lanthanum gallate. Long-term stability of a single-cell stack-unit over 8000 hours was evaluated. The third generation 1 kW-class module has been manufactured for co-generation system demonstration. The targeted 1 kW-AC power output was obtained under thermally self-sustained conditions below 800 °C utilizing commercial town gas with internal steam reforming. The electrical conversion efficiency values of 56%LHV for DC power output and 51%LHV for AC were recorded. Hot water of 90 °C was produced via a heat exchanger utilizing the module exhaust gas. A long-term stability test of the module over 2000 hours was performed. As part of the scaling-up process toward 10 kW-class SOFC system, a triple-stack module was constructed. The output of 3 kW-DC was achieved with the electrical conversion efficiency of 55%LHV. Currently, the fourth generation 1 kW-module designed with compact and simplified structure is being tested. The collaborative efforts are focused on the development of 10 kW-class module in the fiscal year of 2005.

Keywords
solid oxide fuel cell, intermediate-temperature operation, lanthanum gallate, planar disk-type
Source
Proceedings International Hydrogen Energy Congress and Exhibition IHEC 2005 Istanbul, Turkey, 13-15 July 2005
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